Eric W. Cochran
Iowa State University, USA
Title: Bioadvantaged thermoplastic elastomers at iowa state university.
Biography
Biography: Eric W. Cochran
Abstract
In this talk I will present an overview our ongoing work at Iowa State University in the area of bioadvantaged plastics; that is, plastics formed largely from biorenewable resources that offer advantages in cost and utility over their nearest petrochemically derived analogs. ISU has been a leader in this area since the pioneering work of ISU chemistry professor Richard LaRock, the first to convert vegetable oil into thermoset plastics and elastomers. Today, our newly formed NSF Center for Bioplastics and Biocomposites serves the interests of over 20 member companies in the development of new processes and products in the field of biobased polymeric materials. The Cochran Research Group's presence in this area began nearly four years ago with our discovery that controlled radical polymerizations such as ATRP and RAFT* can transform vegetable oils into thermoplastic rubbers. Combined with hard segments such as polystyrene or polymethylmethacrylate, we can produce block copolymers that serve the thermoplastic elastomers industry. We have since applied our technology to other biobased feedstocks, including glycerine, lignin-based phenolic residues, sugars, isosorbide, and lactic acid. This new palette of biomonomers is creating a new array of biobased thermoplastics, asphalt modifiers, sealants, adhesives, and viscosity modifiers that will find commercial success not because they are "green", but rather because they offer unique traits that their competitors cannot. *Atom Transfer Radical Polymerization and Reversible Addition-Fragmentation Chain Transfer polymerization